The bis(hydrogenheptaphosphide)iron(II) dianion: a Zintl ion analogue of ferrocene?
نویسندگان
چکیده
Reaction of K(3)P(7), FeCl(2), [NH(4)][B(C(6)H(5))(4)] and 2,2,2-crypt yielded the unprecedented cluster dianion [Fe(HP(7))(2)](2-). This species was characterized by single crystal X-ray diffraction, multielement NMR spectroscopy and electrospray mass-spectrometry. DFT calculations on the dianion were also conducted.
منابع مشابه
Studies on the reactivity of group 15 Zintl ions with carbodiimides: synthesis and characterization of a heptaphosphaguanidine dianion.
Reaction of the hydrogenheptaphosphide dianion, [HP(7)](2-), with one equivalent of bis(2,6-diisopropylphenyl)carbodiimide yielded the exo-functionalized cluster [P(7)C(NDipp)(NHDipp)](2-) (Dipp = 2,6-diisopropylphenyl). This species was characterized by single crystal X-ray diffraction, multielement NMR spectroscopy and electrospray mass-spectrometry. DFT calculations on the dianion were also ...
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ورودعنوان ژورنال:
- Chemical communications
دوره 47 14 شماره
صفحات -
تاریخ انتشار 2011